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Controlling the morphology of poly(N -cyanoethylpyrrole)

Autor
Fabregat, G.; Aleman, C.; Casas, M.; Armelin, E.
Tipus d'activitat
Article en revista
Revista
Journal of physical chemistry B
Data de publicació
2012-04-26
Volum
116
Número
16
Pàgina inicial
5064
Pàgina final
5070
DOI
https://doi.org/10.1021/jp3008688 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/16598 Obrir en finestra nova
URL
http://pubs.acs.org/doi/pdfplus/10.1021/jp3008688 Obrir en finestra nova
Resum
The morphology of poly(N-cyanoethylpyrrole) has been controlled through the polymerization process. This polymer has been prepared by anodic polymerization, chemical oxidative polymerization in emulsion medium, and layer-by-layer templating polymerization. Anodic polymerization using LiClO4 as supporting electrolyte provides compact films, in which the oxidation degree is controlled through the thickness, useful for the microdetection of dopamine. Chemical polymerization using FeCl3 as oxidant a...
Citació
Fabregat, G. [et al.]. Controlling the morphology of poly(N -cyanoethylpyrrole). "Journal of physical chemistry B", 26 Abril 2012, vol. 116, núm. 16, p. 5064-5070.
Paraules clau
Anodic Polymerization, Chemical Oxidative Polymerization, Chemical Polymerization, Controlled Size, Core-shell Particle, Hollow Microsphere, Internal Structure, Layer-by-layers, Molecular Loadings, Oxidation Degree, Polymerization Process, Supporting Electrolyte, Templating Polymerization, Templating Techniques, Transport Process
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
IMEM-BRT- Innovation in Materials and Molecular Engineering - Biomaterials for Regenerative Therapies
PSEP - Polimers Sintètics: Estructura i Propietats. Polimers Biodegradables.