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High Tg bio-based aliphatic polyesters from bicyclic D-mannitol

Autor
Lavilla, C.; Alla, A.; Martinez de Ilarduya, A.; Muñoz, S.
Tipus d'activitat
Article en revista
Revista
Biomacromolecules
Data de publicació
2013-03-11
Volum
14
Número
3
Pàgina inicial
781
Pàgina final
793
DOI
https://doi.org/10.1021/bm301854c Obrir en finestra nova
Projecte finançador
POLÍMEROS Y NANOPOLÍMEROS DE FUENTES RENOVABLES PARA APLICACIONES BIOMÉDICAS
Repositori
http://hdl.handle.net/2117/18630 Obrir en finestra nova
URL
http://pubs.acs.org/doi/abs/10.1021/bm301854c Obrir en finestra nova
Resum
The carbohydrate-based diol 2,4:3,5-di- O -methylene- D -mannitol (Manx) has been used to obtain aliphatic polyesters. Manx is a symmetric bicyclic compound consisting of two fused 1,3-dioxane rings and bearing two primary hydroxyl groups. In terms of sti ff ness, it is comparable to the widely known isosorbide, but it a ff ords the additional advantages of being much more reactive in polycondensation and capable of producing stereoregular polymers with fairly high molecular weights. A fully bio...
Citació
Lavilla, C. [et al.]. High Tg bio-based aliphatic polyesters from bicyclic D-mannitol. "Biomacromolecules", 11 Març 2013, vol. 14, núm. 3, p. 781-793.
Paraules clau
ACETALIZED GALACTARIC ACID, BIODEGRADABLE POLYMERS, BLOCK, ENZYMATIC DEGRADATION, ISOSORBIDE, POLY(BUTYLENE TEREPHTHALATE) COPOLYESTERS, RENEWABLE RESOURCES, SUCCINATE), UNITS
Grup de recerca
POL - Polímers Industrials Avançats i Biopolímers Tecnològics

Participants