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Pd0.01Ru0.01Ce0.98O2-delta: A highly active and selective catalyst for the liquid phase hydrogenation of p-chloronitrobenzene under ambient conditions

Autor
Mistri, R.; Llorca, J.; Ray, B.C.; Gayen, A.
Tipus d'activitat
Article en revista
Revista
Journal of molecular catalysis A. Chemical
Data de publicació
2013-09
Volum
376
Pàgina inicial
111
Pàgina final
119
DOI
https://doi.org/10.1016/j.molcata.2013.04.018 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/20879 Obrir en finestra nova
Resum
Nanostructured bimetal ion substituted ceria, Pd0.01Ru0.01Ce0.98O2-delta (PdRuC2), prepared for the first time by a novel solution combustion synthesis and characterized employing XRD, BET, HRTEM and XPS has been shown to be very active and selective than the monometal ion substituted analogue Pd0.02Ce0.98O2-delta (PdC2), whereas Ru0.02Ce0.98O2-delta (RuC2) is inactive towards liquid phase hydrogenation of p-chloronitrobenzene to p-chloroaniline under ambient conditions. Structural studies show ...
Citació
Mistri, R. [et al.]. Pd0.01Ru0.01Ce0.98O2-delta: A highly active and selective catalyst for the liquid phase hydrogenation of p-chloronitrobenzene under ambient conditions. "Journal of molecular catalysis A. Chemical", Setembre 2013, vol. 376, p. 111-119.
Paraules clau
Ceria, Chloronitrobenzene hydrogenation, Ionic substitution, PdRu, Ru4+-promotion
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
NEMEN - Nanoenginyeria de materials aplicats a l'energia

Participants

  • Mistri, Rajib  (autor)
  • Llorca Pique, Jordi  (autor)
  • Ray, Bidhan Chandra  (autor)
  • Gayen, Arup  (autor)