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Interactions in dendronized polymers: intramolecular dominates intermolecular

Autor
Cordova, E.; Bertran, O.; Zhang , B.; Vlassopoulos, D.; Pasquino, R.; Schlüter, A.; Kröger , M.; Aleman, C.
Tipus d'activitat
Article en revista
Revista
Soft matter
Data de publicació
2014
Volum
10
Número
7
Pàgina inicial
1032
Pàgina final
1044
DOI
https://doi.org/10.1039/c3sm52343h Obrir en finestra nova
Projecte finançador
POLIMEROS CONDUCTORES Y SUS DERIVADOS HIBRIDOS CON APLICACIONES AVANZADAS
URL
http://pubs.rsc.org/en/Content/ArticleLanding/2014/SM/c3sm52343h#!divAbstract Obrir en finestra nova
Resum
In an attempt to relate atomistic information to the rheological response of a large dendritic object, inter- and intramolecular hydrogen bonds and pi,pi-interactions have been characterized in a dendronized polymer (DP) that consists of a polymethylmethacrylate backbone with tree-like branches of generation four (PG4) and contains both amide and aromatic groups. Extensive atomistic molecular dynamics simulations have been carried out on (i) an isolated PG4 chain and (ii) ten dimers formed by tw...
Paraules clau
ARCHITECTURES, BACKBONE, COMPUTER-SIMULATION, ELECTRON, HOMOLOGOUS SERIES, MOLECULAR-DYNAMICS, ORGANIZATION, PROTEINS, SURFACE, SYSTEM
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
IMEM-BRT- Innovation in Materials and Molecular Engineering - Biomaterials for Regenerative Therapies

Participants