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A versatile thiol-ene/sol-gel two-stage curing process based on a hyperbranched polyester with different degrees of 10-undecenoyl modification

Autor
Flores, Marjorie; Foix, D.; Serra, M. À.; Ramis, X.; Sangermano, M.
Tipus d'activitat
Article en revista
Revista
Macromolecular materials and engineering
Data de publicació
2014-04-01
Volum
299
Número
4
Pàgina inicial
495
Pàgina final
503
DOI
https://doi.org/10.1002/mame.201300264 Obrir en finestra nova
Projecte finançador
Nuevos termoestables mejorados basados en resinas epoxi y polímeros dendríticos
Repositori
http://hdl.handle.net/2117/23215 Obrir en finestra nova
Resum
Hybrid thiol-ene system based on a hyperbranched polyester with different degrees of 10-undecenoyl modification are prepared via a dual UV-thermal process. The pristine thiol-ene formulation shows a high reactivity towards UV curing and the addition of the inorganic precursor to the photocurable formulation does not affect the UV-curing process. The crosslinked systems show an increase of T-g by increasing the vinyl functionality content in the HBP and a T-g increase is also evidenced in the hyb...
Citació
Flores, Marjorie [et al.]. A versatile thiol-ene/sol-gel two-stage curing process based on a hyperbranched polyester with different degrees of 10-undecenoyl modification. "Macromolecular materials and engineering", 01 Abril 2014, vol. 299, núm. 4, p. 495-503.
Paraules clau
Hybrid coatings, Hyperbranched polymers, UV-curing
Grup de recerca
POLTEPO - Polímers Termoestables Epoxídics

Participants

  • Flores Guillen, Marjorie  (autor)
  • Foix, David  (autor)
  • Serra Albet, Maria Àngels  (autor)
  • Ramis Juan, Xavier  (autor)
  • Sangermano, Marco  (autor)