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Improved selectivity for partial oxidation of methane to methanol in the presence of nitrite ions and BiVO4 photocatalyst

Autor
S. Murcia-López; Villa, K.; Andreu, T.; Morante, J.R.
Tipus d'activitat
Article en revista
Revista
Chemical communications
Data de publicació
2015-04-28
Volum
51
Número
33
Pàgina inicial
7249
Pàgina final
7252
DOI
https://doi.org/10.1039/c5cc00978b Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/107685 Obrir en finestra nova
URL
http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC00978B#!divAbstract Obrir en finestra nova
Resum
Nitrite ions are shown to have significant influence on the selectivity of the photocatalytic oxidation of methane to methanol. An almost complete inhibition of undesired CO2 has been achieved with BiVO4 in the presence of a low concentration of nitrite, which might act both as a UV filter and as a hydroxyl radical scavenger.
Citació
S. Murcia-López, Villa, K., Andreu, T., Morante, J.R. Improved selectivity for partial oxidation of methane to methanol in the presence of nitrite ions and BiVO4 photocatalyst. "Chemical communications", 28 Abril 2015, vol. 51, núm. 33, p. 7249-7252.
Paraules clau
bismuth derivative, hydroxyl radical, methane, methanol, nitrate, nitrite, oxygen derivative, vanadium derivative

Participants

  • Murcia López, Sebastián  (autor)
  • Villa Gómez, Katherine  (autor)
  • Andreu Arbella, Teresa  (autor)
  • Morante, Joan Ramon  (autor)