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Poly(alkylene 2,5-furandicarboxylate)s (PEF and PBF) by ring opening polymerization

Autor
Morales, J.; Martinez de Ilarduya, A.; Muñoz, S.
Tipus d'activitat
Article en revista
Revista
Polymer
Data de publicació
2016-03-22
Volum
87
Pàgina inicial
148
Pàgina final
158
DOI
https://doi.org/10.1016/j.polymer.2016.02.003 Obrir en finestra nova
Projecte finançador
Bioplásticos derivados de carbohidratos para envasado y farmacia. Subproyecto II.
Repositori
http://hdl.handle.net/2117/83065 Obrir en finestra nova
URL
http://www.sciencedirect.com/science/article/pii/S0032386116300830 Obrir en finestra nova
Resum
The preparation of cyclic ethylene and butylene 2,5-furandicarboxylate oligoesters and their conversion to furan-based polyesters poly(ethylene furanoate) (PEF) and poly(butylene furanoate) (PBF) by ring-opening polymerization (ROP) are described. The cyclic oligoesters were obtained in high yields by both high dilution condensation and thermal cyclodepolymerization methods, and they consisted of mixtures of small size species. Cyclic dimer, trimer and tetramer oligoesters were isolated by semip...
Citació
Morales, J., Martinez de Ilarduya, A., Muñoz, S. Poly(alkylene 2,5-furandicarboxylate)s (PEF and PBF) by ring opening polymerization. "Polymer", 22 Març 2016, vol. 87, p. 148-158.
Paraules clau
5-furandicarboxylate)s, Cyclic oligoesters, PBF, PEF, ROP, entropically driven ring opening polymerization, poly(alkylen 2
Grup de recerca
POL - Polímers Industrials Avançats i Biopolímers Tecnològics

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