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Tuning supramolecular aurophilic structures: the effect of counterion, positive charge and solvent

Autor
Aguilo, E.; Gavara, R.; Baucells, C.; Guitart, M.; Lima, J.C.; Llorca, J.; Rodríguez, L.
Tipus d'activitat
Article en revista
Revista
Dalton transactions
Data de publicació
2016-01-01
Volum
45
Número
17
Pàgina inicial
7328
Pàgina final
7339
DOI
https://doi.org/10.1039/c6dt00865h Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/88296 Obrir en finestra nova
Resum
The synthesis of the cationic gold(I) complexes [Au(CuCC5H4N)(CH3-PTA)] X (X = I, 1; X = OTf, 4), [Au(C equivalent to CC5H4N-CH3)(PTA)] X (X = I, 2; X = OTf = 5; PTA = 1,3,5-triaza-7-phosphatricyclo[3.3.1.13.7]decane) and [Au(CuCC5H4N-CH3)(DAPTA)] X (X = I, 3; X = OTf = 6, DAPTA = 3,7-diacetyl-1,3,7-triaza-5-phosphabicyclo[ 3.3.1]nonane) results in cationic complexes with unexpected supramolecular assemblies in water ranging from rod-like structures (1) to vesicles (2 and 3) and square-like stru...
Citació
Aguilo, E., Gavara, R., Baucells, C., Guitart, M., Lima, J.C., Llorca, J., Rodríguez, L. Tuning supramolecular aurophilic structures: the effect of counterion, positive charge and solvent. "Dalton transactions", 01 Gener 2016, vol. 45, núm. 17, p. 7328-7339.
Paraules clau
Alkyl chain-length, Alkynylgold(i) complexes, Gold(i) complexes, Photophysical properties, Solid-state, Spectroscopic properties, water
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
NEMEN - Nanoenginyeria de materials aplicats a l'energia

Participants

  • Aguilo Linares, Elisabet  (autor)
  • Gavara, Raquel  (autor)
  • Baucells, Clara  (autor)
  • Guitart, Marta  (autor)
  • Lima, Joao Carlos  (autor)
  • Llorca Pique, Jordi  (autor)
  • Rodríguez Raurell, Laura  (autor)

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