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Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization

Autor
Konuray, A.; Fernandez-Francos, X.; Serra, M. À.; Ramis, X.
Tipus d'activitat
Article en revista
Revista
European polymer journal
Data de publicació
2016-11
Volum
84
Pàgina inicial
256
Pàgina final
267
DOI
https://doi.org/10.1016/j.eurpolymj.2016.09.025 Obrir en finestra nova
Projecte finançador
Nuevos termoestables multifuncionales obtenidos mediante curado dual
Repositori
http://hdl.handle.net/2117/101147 Obrir en finestra nova
URL
http://www.sciencedirect.com/science/article/pii/S0014305716306863 Obrir en finestra nova
Resum
Dual curing systems find various uses in industry with the process flexibility they provide which allows tailoring properties at different curing stages in accordance with application requirements. A safe and efficient dual curing scheme is proposed here for a set of mixtures containing different proportions of acrylates and methacrylates. The first curing stage is a stoichiometric aza-Michael addition between acrylates and an amine, followed by photo-initiated radical homopolymerization of meth...
Citació
Konuray, A., Fernandez-Francos, X., Serra, À., Ramis, X. Sequential curing of amine-acrylate-methacrylate mixtures based on selective aza-Michael addition followed by radical photopolymerization. "European polymer journal", Novembre 2016, vol. 84, p. 256-267.
Paraules clau
Acrylate, Aza-Michael, Click reaction, Dual curing, Methacrylate, Photopolymerization
Grup de recerca
POLTEPO - Polímers Termoestables Epoxídics

Participants