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Synthesis of vegetable-oil based polymer by terpolymerization of epoxidized soybean oil, propylene oxide and carbon dioxide

Autor
Md Shaarani, S.; Bou, J. J.
Tipus d'activitat
Article en revista
Revista
Science of the total environment
Data de publicació
2017-11-15
Volum
598
Pàgina inicial
931
Pàgina final
936
DOI
https://doi.org/10.1016/j.scitotenv.2017.04.184 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/104819 Obrir en finestra nova
URL
http://www.sciencedirect.com/science/article/pii/S004896971731029X Obrir en finestra nova
Resum
Although carbon dioxide (CO2) is well known as one of the major green-house gases, it is also an economical C1 resource. Thus, CO2 has been regarded as an appealing starting material for the synthesis of polymers, like polycarbonates by the reaction with epoxides. Herein the reaction between natural epoxidized soybean oil (ESO), propylene oxide (PO) and CO2 under high pressure (4.0 MPa) with the presence of Co-Zn double metal cyanide (Co-Zn DMC) catalyst was studied. Temperature and reaction tim...
Paraules clau
Renewable Bio-resources, Natural Epoxide, Double Metal Cyanide, Bio-based Polymer, Polycarbonate
Grup de recerca
Càtedra A3 ENGIBIO - Càtedra A3 d’Innovació en Cuir, Moda i Tèxtils

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