Carregant...
Carregant...

Vés al contingut (premeu Retorn)

On the microscopic mechanism behind the purely orientational disorder-disorder transition in the plastic phase of 1-chloroadamantane

Autor
Vispa, A.; Monserrat, D.; Cuello, G. J.; Fernandez-Alonso, F.; Mukhopadhyay, S.; Demmel, F.; Tamarit, J. Ll.; Pardo, L.
Tipus d'activitat
Article en revista
Revista
Physical chemistry chemical physics
Data de publicació
2017-08-14
Volum
19
Número
30
Pàgina inicial
20259
Pàgina final
20266
DOI
https://doi.org/10.1039/c7cp03630b Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/109700 Obrir en finestra nova
URL
http://pubs.rsc.org/en/Content/ArticleLanding/2017/CP/C7CP03630B#!divAbstract Obrir en finestra nova
Resum
Globular molecules of 1-chloroadamantane form a plastic phase in which the molecules rotate in a restrained way, but with their centers of mass forming a crystalline ordered lattice. Plastic phases can be regarded as test cases for the study of disordered phases since, contrary to what happens in the liquid phase, there is a lack of stochastic translational degrees of freedom. When the temperature is increased, a hump in the specific heat curve is observed indicating a change in the energetic fo...
Citació
Vispa, A., Monserrat, D., Cuello, G. J., Fernandez-Alonso, F., Mukhopadhyay, S., Demmel, F., Tamarit, J. Ll., Pardo, L. On the microscopic mechanism behind the purely orientational disorder-disorder transition in the plastic phase of 1-chloroadamantane. "Physical chemistry chemical physics", 14 Agost 2017, vol. 19, núm. 30, p. 20259-20266.
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
GCM - Grup de Caracterització de Materials

Participants

Arxius