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A green strategy for the synthesis of poly(ethylene succinate) and its copolyesters via enzymatic ring opening polymerization

Autor
Morales, J.; Martinez de Ilarduya, A.; Muñoz, S.
Tipus d'activitat
Article en revista
Revista
European polymer journal
Data de publicació
2017-10
Volum
95
Pàgina inicial
514
Pàgina final
519
DOI
https://doi.org/10.1016/j.eurpolymj.2017.08.043 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/107793 Obrir en finestra nova
URL
http://www.sciencedirect.com/science/article/pii/S0014305717313083?via%3Dihub Obrir en finestra nova
Resum
Poly(ethylene succinate) (PES) with weight-average molecular weight above 60,000 g mol-1 was efficiently obtained by enzymatic ring opening polymerization of cyclic oligo(ethylene succinate)s c(ES)n, which in turn were prepared by lipase-catalysed cyclocondensation in solution of dimethyl succinate and ethylene glycol. The methodology was demonstrated to be also applicable to the synthesis of high molecular weight PES-copolyesters containing butylene succinate, e-hydroxycaproate or L-lactate uni...
Citació
Morales, J., Martinez de Ilarduya, A., Muñoz, S. A green strategy for the synthesis of poly(ethylene succinate) and its copolyesters via enzymatic ring opening polymerization. "European polymer journal", Octubre 2017, vol. 95, p. 514-519.
Paraules clau
Cyclic Oligoesters, Enzymatic Synthesis, Poly(ethylene Succinate), Rop
Grup de recerca
POL - Polímers Industrials Avançats i Biopolímers Tecnològics