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Phloretic acid as an alternative to the phenolation of aliphatic hydroxyls for the elaboration of polybenzoxazine

Autor
Trejo, A.; Verge, P.; Puchot, L.; Quintana, R.
Tipus d'activitat
Article en revista
Revista
Green chemistry
Data de publicació
2017-11-07
Volum
19
Número
21
Pàgina inicial
5065
Pàgina final
5073
DOI
https://doi.org/10.1039/c7gc02348k Obrir en finestra nova
URL
http://pubs.rsc.org/en/Content/ArticleLanding/2017/GC/C7GC02348K#!divAbstract Obrir en finestra nova
Resum
3-(4-Hydroxyphenyl)propanoic acid, so-called phloretic acid (PA), is a naturally occurring phenolic compound which can be produced by the hydrogenation of p-coumaric acid or synthesized from phloretin, a by-product of apple tree leaves. It is explored herein as a renewable building block for enhancing the reactivity of –OH bearing molecules towards benzoxazine (Bz) ring formation instead of phenol. PA is used to bring phenolic functionalities by its reaction with model molecules (ethylene glyc...

Participants

  • Trejo Machin, Acerina  (autor)
  • Verge, Pierre  (autor)
  • Puchot, Laura  (autor)
  • Quintana Vicente, Roberto  (autor)