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Poly(2-thiophene-3-yl-malonic acid), a Polythiophene with Two Carboxylic Acids Per Repeating Unit

Autor
Bertran, O.; Armelin, E.; Estrany, F.; Gomes, A.L.; Torras, J.; Aleman, C.
Tipus d'activitat
Article en revista
Revista
Journal of physical chemistry B
Data de publicació
2010-04-22
Volum
114
Pàgina inicial
6281
Pàgina final
6290
DOI
https://doi.org/10.1021/jp1006796 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/7429 Obrir en finestra nova
URL
http://pubs.acs.org/doi/abs/10.1021%2Fjp1006796 Obrir en finestra nova
Resum
A new substituted polythiophene derivative bearing malonic acid, poly(2-thiophen-3-yl-malonic acid), has been prepared and characterized using a strategy that combines both experimental and theoretical methodologies. The chemical structure of this material has been investigated using FTIR and 1H NMR, and its molecular conformation has been determined using quantum mechanical calculations. Interestingly, the arrangement of the inter-ring dihedral angles was found to depend on the ionization degre...
Citació
Bertran, O. [et al.]. Poly(2-thiophene-3-yl-malonic acid), a Polythiophene with Two Carboxylic Acids Per Repeating Unit. "Journal of physical chemistry B", 22 Abril 2010, vol. 114, p. 6281-6290.
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
IMEM-BRT- Innovation in Materials and Molecular Engineering - Biomaterials for Regenerative Therapies

Participants