FUTUR. Portal de la Producció Científica dels Investigadors de la UPC.

Macromolecules

Total activitats: 73

ISSN: 0024-9297
Editorial: American Chemical Society (ACS)

Producció científica

1 a 50 de 73 resultats

Ordenar per:

Dielectric relaxations in poly(glycidyl phenyl ether): Effects of microstructure and cyclic topology
Gambino, T.; Martinez de Ilarduya, A.; Alegría, A.; Barroso, F.
Macromolecules
Vol. 49, num. 3, p. 1060-1069
DOI: 10.1021/acs.macromol.5b02687
Data de publicació: 2016-02-09
Article en revista
Cyclic and linear, isoregic and aregic, and isotactic and atactic poly(glycidyl phenyl ether) (PGPE) with molecular weights up to Mw = 5.5 kg/mol are synthesized by ring-opening polymerization of glycidyl phenyl ether. Initiation with tetrabutylammonium fluoride leads to isoregic linear polymers with ~95% regular linkages, and initiation with B(C6F5)3 and B(C6F5)3/water leads to aregic cyclic and linear polymers, respectively, with ~50% regular linkages as quantified by 13C NMR. Local, segmental, and chain dynamics in PGPE is investigated by broadband dielectric spectroscopy (10–2–106 Hz). The ß-relaxation for linear PGPE is separated into two contributions arising from the motions of side groups and end groups with activation energies of 35.4 and 23.8 kJ/mol, respectively. The ß-relaxation process for cyclic PGPE shows the same activation energy as that shown by the side-group contribution in linear PGPE, indicating that topology does not play a key role on the side-group local dynamics. Moreover, cyclic PGPE samples show higher calorimetric and dynamic glass transition temperatures as well as lower dynamic fragility compared to linear chains. Unexpectedly from topological considerations, cyclic PGPE shows low frequency dielectric contributions that can be attributed to short wavelength internal ring motions and that are detectable by dielectric relaxation due to the aregic nature of the rings.
Nucleation and antinucleation effects of functionalized carbon nanotubes on cyclic and linear Poly(e-caprolactones)
Perez, R.; Lopez, J.; Hoskins, J.; Zhang, B.; Grayson, S.; Casas, M.; Puiggali, J.; Muller, A.
Macromolecules
Vol. 47, num. 11, p. 3553-3566
DOI: 10.1021/ma5005869
Data de publicació: 2014-06-10
Article en revista
Novel nanocomposites were prepared by blending linear or cyclic poly(e-caprolactones) with two types of chemically modified carbon nanotubes (CNTs). The low-polydispersity cyclic PCL samples (C-PCLs) were synthesized by click chemistry with a number-average molecular weight (M n) of 22 kg/mol. Linear analogues (L-PCLs) with the same M n value were also prepared. Two types of CNTs were employed (with 1% w/w content): single wall CNTs functionalized with octadecylamine (SWNT-ODA) and multiwall carbon nanotubes grafted with linear PCL chains (i.e., MWNT-g-PCL prepared by ring-opening polymerization on previously functionalized MWNTs with a composition of 10% MWNT and 90% L-PCL). The nanocomposites were characterized by transmission electron microscopy (TEM), polarized light optical microscopy (PLOM), and differential scanning calorimetry (DSC). A nucleating effect was detected in both PCLs when SWNT-ODAs were employed. However, in the case of MWNT-g-PCL, the nanofiller nucleated L-PCL but caused an unexpected antinucleation effect on C-PCL. Another interesting behavior displayed by this novel C-PCL/MWNT-g-PCL nanocomposite (composed of 90% C-PCL, 9% L-PCL, and 1% MWNTs) was not only a reduction in nucleation density and in Tc temperatures during cooling from the melt, as expected for an antinucleating agent, but also a decrease in spherulitic growth rate and in overall isothermal crystallization kinetics as compared to C-PCL. The results were explained by realizing that new topological effects were created upon mixing the grafted L-PCL chains within MWNT-g-PCL with C-PCL molecules. When these linear chains come into contact with cyclic PCL chains, a threading effect is produced that dramatically affects chain dynamics by forming a transient entanglement network. As a consequence, cyclic molecules relax and diffuse more slowly than anticipated, decreasing both nucleation and growth kinetics. Results on linear and cyclic PCL blends are also presented here, and they support our explanation of the unexpected antinucleation effect reported for C-PCL/MWNT-g-PCL nanocomposites.
Solid-state modification of PBT with cyclic acetalized galactitol and D-mannitol: Influence of composition and chemical microstructure on thermal properties
Lavilla, C.; Gubbels, E.; Martinez de Ilarduya, A.; Noordover, B.; Koning, Cornelis Eme; Muñoz, S.
Macromolecules
Vol. 46, num. 11, p. 4335-4345
DOI: 10.1021/ma400760d
Data de publicació: 2013-06-11
Article en revista
Two bicyclic carbohydrate-based diols, 2,3:4,5-di-O-methylene-galactitol or 2,4:3,5-di-O-methylene-D-mannitol, were introduced into the backbone of poly(butylene terephthalate) using the solid-state modification technique. The resulting copolyesters had a unique block-like chemical microstructure that endows them with superior thermal properties when compared with their random counterparts obtained by melt copolymerization. The materials prepared by SSM displayed higher melting points, crystallization temperatures, and crystallinity due to the presence of long PBT sequences in the copolyester. The glass-transition temperatures also increased upon incorporation of the bicyclic comonomers, this effect being more pronounced for Manx units. SSM was demonstrated to be a very suitable technique for the incorporation of rigid monomers into the amorphous phase of PBT, leading to bio-based non-random copolyesters with remarkable thermal properties

Two bicyclic carbohydrate-based diols, 2,3:4,5- di- O -methylene-galactitol (Galx) or 2,4:3,5-di- O -methylene- D - mannitol (Manx), were introduced into the backbone of poly(butylene terephthalate) using the solid-state modi fi cation technique (SSM). The resulting copolyesters had a unique block-like chemical microstructure that endows them with superior thermal properties when compared with their random counterparts obtained by melt copolymerization. The materials prepared by SSM displayed higher melting points, crystal- lization temperatures, and crystallinity due to the presence of long PBT sequences in the copolyester. The glass-transition temperatures also increased upon incorporation of the bicyclic comonomers, this e ff ect being more pronounced for Manx units. The melting points of these block-like copolyesters decreased after melting due to the occurrence of randomization, but they remained higher than those of copolyesters prepared from the melt. SSM was demonstrated to be a very suitable technique for the incorporation of rigid monomers into the amorphous phase of PBT, leading to bio-based non-random copolyesters with remarkable thermal properties
Comblike Ionic Complexes of Poly(gamma-glutamic acid) and Alkanoylcholines Derived from Fatty Acids
Tolentino, A.; León, S.; Alla, A.; Martinez de Ilarduya, A.; Muñoz, S.
Macromolecules
Vol. 46, num. 4, p. 1607-1617
DOI: 10.1021/ma3026783
Data de publicació: 2013-02-15
Article en revista
A series of ionic complexes with almost stoichio- metric composition have been “ synthesized ” from bacterial poly( γ - glutamic acid) and alkanoylcholines derived from fatty acids with 12, 14, 16, and 18 carbon atoms. The complexes were stable up to temperatures close to 200 ° C and were non-water-soluble but readily soluble in organic solvents. In the solid state they adopted the biphasic structure typical of comblike systems with the polypeptide chains arranged in sheets and periodically separated by a para ffi nic phase which was partially crystallized for C14, C16, and C18. The window width of the layered structure was estimated by SAXS to be within the 3.6 − 4.5 nm range, and WAXS showed that the alkyl tails were crystallized in a hexagonally packed lattice with a d 100 spacing of 0.41 nm. These complexes displayed reversible melting of the para ffi nic phase in the 40 − 65 ° C range at temperatures with values increasing with the length of the alkanoyl group. A slight expansion of the intersheet distance occurred at melting followed by contraction upon heating at higher temperatures but without signi fi cant alteration of the layered structure. The 13 C CP-MAS NMR analysis revealed the underlying polymethylene anti -to- gauche conformational conversion that takes place at the thermal transition. An energy-based simulation study of the crystallization process a ff orded a molecular picture of the complex and evidenced the favoring e ff ect of the choline structure on the packing of the alkyl side
Linear viscoelastic response of dendronized polymers
Pasquino, R.; Zhang , B.; Sigel, R.; Yu, H.; Ottiger, M.; Bertran, O.; Aleman, C.; Schlüter, A.; Vlassopoulos, D.
Macromolecules
Vol. 45, num. 21, p. 8813-8823
DOI: 10.1021/ma301029t
Data de publicació: 2012-11-13
Article en revista
Bio-based aromatic polyesters from a novel bicyclic diol derived from D-mannitol
Lavilla, C.; Martinez de Ilarduya, A.; Alla, A.; García-Martín, M.G.; Galbis Pérez, Juan Antonio; Muñoz, S.
Macromolecules
Vol. 45, num. 20, p. 8257-8266
DOI: 10.1021/ma3013288
Data de publicació: 2012-10-23
Article en revista
2,4:3,5-Di-O-methylene-D-mannitol, abbreviated as Manx, is a D-mannitol-derived compound with the secondary hydroxyl groups acetalized with formaldehyde. The bicyclic structure of Manx consists of two fused 1,3-dioxane rings, with two primary hydroxyl groups standing free for reaction. A homopolyester made of Manx and dimethyl terephthalate as well as a set of copolyesters of poly(butylene terephthalate) (PBT) in which 1,4-butanediol was replaced by Manx up to 50% were synthesized and characterized. The polyesters had Mw in the 30 000−52 000 g mol−1 range and a random microstructure and were thermally stable up to nearly 370 °C. They displayed outstanding high Tg with values from 55 to 137 °C which steadily increased with the content in Manx. Copolyesters containing up to 40% of Manx were semicrystalline and adopted the crystal structure of PBT. Their stress− strain parameters were sensitively affected by the presence of carbohydrate-based units with elongation at break decreasing but tensile strength and elastic moduli steadily increasing with the degree of replacement.
Field-Induced Transport in Sulfonated Poly(styrene-co-divinylbenzene) Membranes
Bertran, O.; Curcó, D.; Torras, J.; Ferreira, C.A.; Aleman, C.
Macromolecules
Vol. 43, num. 24, p. 10521-10527
DOI: 10.1021/ma102500w
Data de publicació: 2010-12-06
Article en revista
Atomistic simulations have been carried to investigate electric field induced transport of hydronium ions in a sulfonated poly(styrene-co-divinylbenzene) membrane. In order to provide a good description of this cross-linked material, a methodology has been explicitly designed to construct a reliable model of the hydrated membrane. This model has been used to carry out molecular dynamics simulations in presence of electric fields, which varied from 0.001 to 3.0 V3 nm-1. Results show that the electric field affects the structure of the membrane producing both a redistribution of the unoccupied volume, which modifies the heterogeneity of the resin, and a rearrangement of the negatively charged sulfonate groups, which undergo a systematic alignment along the electric field direction. As was expected, the mobility of hydronium ions is enhanced with the strength of the electric field. Moreover, the electric field induces a significant rearrangement of the sulfonate groups, which is evidenced by the alignment of theC-S bonds along the direction of the field. The membrane has been found to behave as a spring, in which the force exerted by the electric field acts in opposite sense to the force exerted by the internal structure of the cross-linked material.
The Role of Chain Length in Nonergodicity Factor and Fragility of Polymers
Dalle, C.; Niss, K.; Sokolov, A.; Frick, B.; Serrano, J.; Alba
Macromolecules
Vol. 43, num. 21, p. 8977-8984
DOI: 10.1021/ma101622f
Data de publicació: 2010-11-09
Article en revista
Sequence analysis of polyether-based thermoplastic polyurethane elastomers by 13C NMR
Martinez de Ilarduya, A.; Carvalho, E.; Alla, A.; Muñoz, S.
Macromolecules
Vol. 43, num. 8, p. 3990-3993
DOI: 10.1021/ma100395x
Data de publicació: 2010-04-27
Article en revista
In this Note we would like to report on the analysis of the microstructure of segmented polyurethanes by 13CNMRmaking use of the signals arising from nonprotonated aromatic carbons which appear to be sensitive to dyads sequence distribution. The polyurethanes here studied were obtained from poly(tetramethylene glycol) (PTMG) as macrodiol soft segment, 1,4-butanediol (BD) chain extender, and 4,40'-methylenediphenyl diisocyanate (MDI) as hard segment.The results obtained in this work provide a relatively simple and reliable method to determine the microstructure of MDI-based thermoplastic polyurethanes by means of the NMR technique.
Crystal Structure and Morphology of Linear Aliphatic n-Polyurethanes
Fernandez, C.E.; Bermudez, M.; Muñoz, S.; León, S.; Versteegen, R.; Meijer, E.W
Macromolecules
Vol. 43, num. 9, p. 4161-4171
DOI: 10.1021/ma100299p
Data de publicació: 2010-04-12
Article en revista
Poly(hexamethylene terephthalate-co-caprolactone) Copolyesters Obtained by Ring-Opening Polymerization
González, N.; Martinez de Ilarduya, A.; Herrera, V.; Muñoz, S.
Macromolecules
Vol. 41, num. 12, p. 4136-4146
Data de publicació: 2008-06
Article en revista
Structural and electronic properties of crown ether functionalized oligothiophenes
Casanovas Salas, Jordi; Zanuy, D.; Aleman, C.
Macromolecules
Vol. 41, num. 11, p. 3919-3924
DOI: 10.1021/ma800174b
Data de publicació: 2008-06
Article en revista
Spectroscopic Evidence for Stereocomplex Formation by Enantiomeric Polyamides Derived from Tartaric Acid
Martín, R.; Martinez de Ilarduya, A.; Romero, P.; Sarasua, J.; Meaurio, E.; Zuza, E.; Muñoz, S.
Macromolecules
Vol. 41, num. 10, p. 3734-3738
Data de publicació: 2008-05
Article en revista
Poly(butylene terephthalate) Copolyesters Derived from L-Arabinitol and Xylitol
Alla, A.; Hakkou, K.; Zamora, F.; Martinez de Ilarduya, A.; Galbis Pérez, Juan Antonio; Muñoz, S.
Macromolecules
Vol. 39, num. 4, p. 1410-1416
Data de publicació: 2006-02
Article en revista
Carbohydrate-based polycarbonates Synthesis, structure, and biodegradation studies
García-Martín, M.G.; Ruíz-Pérez, R.; Benito-Hernández, E.; Espartero, J.; Muñoz, S.; Galbis Pérez, Juan Antonio
Macromolecules
Vol. 38, num. 21, p. 8664-8670
Data de publicació: 2005-10
Article en revista
Molecular packing of polyesters derived from 1,4-butanediol and even aliphatic dicarboxylic acids
Almontassir, A.; Gestí, S.; Franco, M.; Puiggali, J.
Macromolecules
Vol. 37, num. 14, p. 5300-5309
Data de publicació: 2004-07
Article en revista
Poly(ester amide)s Derived from L-Malic Acid
Regaño, C.; Alla, A.; Martinez de Ilarduya, A.; Muñoz, S.
Macromolecules
Vol. 37, num. 6, p. 2067-2075
Data de publicació: 2004-03
Article en revista
Synthesis and Properties of Poly(D-mannaramide)s and Poly(galactaramide)s
Mancera, M.; Zamora, F.; Roffé, I.; Bermudez, M.; Alla, A.; Muñoz, S.; Galbis Pérez, Juan Antonio
Macromolecules
Vol. 37, num. 8, p. 2779-2783
Data de publicació: 2004-01
Article en revista
Synthesis and Characterization of Linear Polyamides Derived from L-Arabinitol and Xylitol
García-Martín, M.G.; Hernandez, B.; Perez, R.; Alla, A.; Muñoz, S.; Galbis Pérez, Juan Antonio
Macromolecules
Vol. 37, num. 15, p. 5550-5556
Data de publicació: 2004-01
Article en revista
Synthesis and characterization of a new degradable poly(ester amide) derived from 6-amino-1-hexanol and glutaric acid
Rodriguez, R.; Puiggali, J.
Macromolecules
Vol. 36, num. 26, p. 9784-9796
Data de publicació: 2003-12
Article en revista
Comblike Alkyl Esters of Biosynthetic Poly(gamma-glutamic acid). 2. Supramolecular Structure and Thermal Transitions
Morillo, M.; Martinez de Ilarduya, A.; Alla, A.; Muñoz, S.
Macromolecules
Vol. 36, num. 20, p. 7567-7576
Data de publicació: 2003-10
Article en revista
On the crystalline structure of poly(tetramethylene adipate)
Pouget, E.; Almontassir, A.; Casas, M.; Puiggali, J.
Macromolecules
Vol. 36, num. 3, p. 698-705
Data de publicació: 2003-02
Article en revista
On the crystalline structure of even polyoxalamides
Casas, M.; Armelin, E.; Aleman, C.; Puiggali, J.
Macromolecules
Vol. 35, num. 23, p. 8781-8787
DOI: 10.1021/ma020869x
Data de publicació: 2002-11
Article en revista
On the crystal structure of poly(alpha-benzyl gamma,DL-glutamate) of microbial origin
Melis, J.; Zanuy, D.; Aleman, C.; Garcia, M.; Muñoz, S.
Macromolecules
Vol. 35, num. 23, p. 8774-8780
Data de publicació: 2002-11
Article en revista
Permeation properties of the stereoregular nylon 3 analogue, poly(alpha-hexyl-beta-L-aspartate)
Compañ, V.; Zanuy, D.; Andrio, A.; Morillo, M.; Aleman, C.; Muñoz, S.
Macromolecules
Vol. 35, num. 11, p. 4521-4530
Data de publicació: 2002-05
Article en revista
Crystalline structure of poly(decamethylene sebacate). Repercussions on lamellar folding surfaces
Armelin, E.; Almontassir, A.; Franco, M.; Puiggali, J.
Macromolecules
Vol. 35, num. 9, p. 3630-3635
DOI: 10.1021/ma011918t
Data de publicació: 2002-04-23
Article en revista
Sequence Analysis of Poly(ethylene terephthalate) Terpolyesters Containing Isophthalic and tert-Butyl Isophthalic Units by 13C NMR
Kint, D.; Martinez de Ilarduya, A.; Muñoz, S.
Macromolecules
Vol. 35, num. 1, p. 314-317
Data de publicació: 2002-01
Article en revista
Conformational behavior of macromolecules in solution. Homopolypeptides of alpha-aminoisobutyric acid as test cases
Robertor, I.; Nadia, R.; Aleman, C.; Vincenzo, B.
Macromolecules
Vol. 34, num. 24, p. 7550-7557
Data de publicació: 2001-12
Article en revista
Comblike Alkyl Esters of Biosynthetic Poly(gamma-glutamic acid). 1. Synthesis and Characterization
Morillo, M.; Martinez de Ilarduya, A.; Muñoz, S.
Macromolecules
Vol. 34, num. 22, p. 7868-7875
Data de publicació: 2001-10
Article en revista
Synthesis and Structural Studies of 2,3-Disubstituted Poly(beta-peptide)s
García-Martín, M.G.; Viloante, M.; Muñoz, S.; Garcia, M.; Galbis Pérez, Juan Antonio
Macromolecules
Vol. 34, num. 14, p. 5042-5047
Data de publicació: 2001-06
Article en revista
On the crystal structure of the alpha-form of poly(L-lactide)
Aleman, C.; Puiggali, J.
Macromolecules
Vol. 34, p. 4795-4802
Data de publicació: 2001-05
Article en revista
Structure of the extended crystal forms of nylon-6
León, S.; Aleman, C.; Muñoz, S.
Macromolecules
Vol. 33, num. 33, p. 5754-5756
Data de publicació: 2000-12
Article en revista
Structure of nylon 46 lamellar crystals: An investigation including adjacent chain folding
Leon, S.; Aleman, C.; Bermudez, M.; Muñoz, S.
Macromolecules
Vol. 33, p. 8756-8763
Data de publicació: 2000-11
Article en revista
Structure of a Cyclic Trimer as a Model of Nylon 11. Folding at Lamellar Surfaces
Escudero, E.; Subirana, J.
Macromolecules
Vol. 34, p. 837-843
Data de publicació: 2000-11
Article en revista
Packing of sequencial poly(ester amide)s derived from diols, dicarboxylic acids, and amino acids
Paredes, N.; Casas, M.; Puiggali, J.
Macromolecules
Vol. 33, p. 9090-9101
Data de publicació: 2000-08
Article en revista
Application of the Adam-Gibbs Equation to the Non-Equilibrium Glassy State
Hutchinson, J.M.; Montserrat, S.; Calventus, Y.; Cortes, M.
Macromolecules
Vol. 33, num. 14, p. 5252-5262
DOI: 10.1021/ma992015r
Data de publicació: 2000-07
Article en revista
Sequence analysis of poly(ethylene terephthalate-co-isophthalate) copolymers by 13c nmr
Martinez de Ilarduya, A.; Kint, D.; Muñoz, S.
Macromolecules
Vol. 33, num. 12, p. 4596-4598
Data de publicació: 2000-06
Article en revista
Stereoregular copolyamides derived from D-xylose and L-arabinose
Zamora, F.; Bueno, M.; Molina, I.; Iribarren, J.; Muñoz, S.
Macromolecules
Vol. 33, p. 2030-2038
DOI: 10.1021/ma9916436
Data de publicació: 2000-02
Article en revista
Hydrolytic degradation of poly(ester amide)s made from tartaric and succinic acids: Influence of chemical structure and microstructure on degradation rate
Villuendas, M.; Molina, I.; Regaño, C.; Bueno, M.; Martinez de Ilarduya, A.; Galbis Pérez, Juan Antonio; Muñoz, S.
Macromolecules
Vol. 32, num. 24, p. 8033-8040
Data de publicació: 1999-11
Article en revista
Influence of hydroxy functionalization and metal cross-linking on fiber properties of liquid-crystalline polyazomethines
Cerrada, P.; Oriol, L.; Piñol, M.; Serrano, J.; Alonso, P.; Puértolas, J.; Iribarren, J.; Muñoz, S.
Macromolecules
Vol. 32, p. 3565-3573
DOI: 10.1021/ma9812837
Data de publicació: 1999-11
Article en revista
Poly(ester amide)s Derived from l-Tartaric Acid and Amino Alcohols. 1. Regic Polymers
Villuendas, I.; Iribarren, J.; Muñoz, S.
Macromolecules
Vol. 32, p. 8015-8023
DOI: 10.1021/ma991050v
Data de publicació: 1999-11
Article en revista
Helical poly(beta-peptides): The helix-coil transition of poly(alpha-alkyl-beta-aspartate)s in solution
Martinez de Ilarduya, A.; Aleman, C.; Garcia, M.; Lopez, F.; Muñoz, S.
Macromolecules
Vol. 32, num. 10, p. 3257-3263
Data de publicació: 1999-05
Article en revista
Crystal structures of nylon 5,6. A model with two hydrogen bond directions for nylons derived from odd diamines
Puiggali, J.; Franco, M.; Aleman, C.; Subirana, J.
Macromolecules
Vol. 31, num. 23, p. 8540-8548
Data de publicació: 1998-12
Article en revista
Structure and morphology of odd polyoxamides [NYLON 9,2]. A new example of hydrogen bonding interactions in two different directions
Franco, M.; Subirana, J.; Puiggali, J.
Macromolecules
Vol. 31, num. 12, p. 3912-3924
Data de publicació: 1998-06
Article en revista
Simulation of polymer crystallization through a dynamic Monte Carlo lattice model
Toma, L.; Toma, S.; Subirana, J.
Macromolecules
Vol. 31, num. 7, p. 2328-2334
Data de publicació: 1998-05
Article en revista
Helicol nylon 3. Synthesis and crystal structure of poly (ß-L-aspartate)s with branched alkyl side chains
Garcia, M.; Leon, S.; Aleman, C.; Campos, J.Lourdes; Muñoz, S.
Macromolecules
Vol. 31, p. 124-134
Data de publicació: 1998-01
Article en revista
Crystallographic and quantum mechanical results on y[NHCO] aliphatic diamides. the number of methylenes strongly influences their structural and conformational properties
NAVARRO, E.; Aleman, C.; Puiggali, J.
Macromolecules
Vol. 31, num. 2, p. 408-416
Data de publicació: 1998-01
Article en revista
Polyamides with a choice of structure and crystal surface chemistry. Studies of chain-folded lamellae of nylons 8 10 and 10 12 and comparison with the other 2N 2(N+1) nylons 46 and 68
Jones, N.; Atkins, E.; Hill, M.; Cooper, S.; Franco, M.
Macromolecules
Vol. 30, num. 12, p. 3569-3578
Data de publicació: 1997-06
Article en revista
Structural study on poly (beta-L-aspartate)s with short alkyl side chains: Helical and extended crystal forms
Lopez-Carrasquero, F.; Garcia, M.; Navas, J.; Aleman, C.; Muñoz, S.
Macromolecules
Vol. 29, num. 26, p. 8449-8459
Data de publicació: 1996-12
Article en revista
Stereocopolyamides derived from 2,3-di-O-methyl-d and L-tartaric acids and hexamethylenediamine.II. Influence of the configurational composition on the crystal structure of optically compensated systems
Iribarren, J.; Aleman, C.; Regaño, C.; Martinez de Ilarduya, A.; Bou, J. J.; Muñoz, S.
Macromolecules
Vol. 29, num. 26, p. 8413-8424
Data de publicació: 1996-12
Article en revista

Macromolecules

Producció científica

Tipus d'activitat

Activitat en accés obert

Campus