Del Barrio, M.; Levit, R.; Lloveras, P.; Aznar, A.; Negrier, P.; Mondieig, D.; Tamarit, J. Ll. Fluid phase equilibria Vol. 459, p. 219-229 DOI: 10.1016/j.fluid.2017.07.020 Data de publicació: 2018-03-15 Article en revista
The temperature-composition phase diagram of the two-component system 1-Br-adamantane and 1-Cl-adamantane has been determined by means of thermal analysis techniques and X-ray powder diffraction from the low-temperature phase to the liquid state.
The crossed isopolymorphism formalism has been applied to the two-component system to infer the normal pressure properties of the orthorhombic metastable phase of 1-Cl-adamantane at normal pressure. The experimental pressure-temperature phase diagrams for the involved compounds are related to the two-phase equilibria determined at normal pressure and inferences about the monotropic behavior of the aforementioned orthorhombic phase are discussed.