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Brill transition and melt crystallization of nylon 56: An odd–even polyamide with two hydrogen-bonding directions

Autor
Morales, L.; Soto, D.; Franco, M.; Puiggali, J.
Tipus d'activitat
Article en revista
Revista
Polymer
Data de publicació
2010-11-12
Volum
51
Número
24
Pàgina inicial
5788
Pàgina final
5798
DOI
https://doi.org/10.1016/j.polymer.2010.09.074 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/10932 Obrir en finestra nova
Resum
Brill transition and crystallization behaviour of nylon 56, a representative polymer of odd–even polyamides, were investigated by simultaneous WAXD and SAXS synchrotron radiation. Nylon 56 crystallized from solution into a peculiar structure where hydrogen bonds were established along the two directions. Nylon 56 experimented on heating a Brill transition that lead to a pseudohexagonal packing and lately to a monoclinic unit cell where neighbouring molecular segments were shifted along the cha...
Citació
Morales, L. [et al.]. Brill transition and melt crystallization of nylon 56 an odd-even polyamide with two hydrogen-bonding directions. "Polymer", 12 Novembre 2010, vol. 51, núm. 24, p. 5788-5798.
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
PSEP - Polimers Sintètics: Estructura i Propietats. Polimers Biodegradables.

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