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From figh-temperature orientationally disordered mixed crystals to low-temperature complex formation in the two-component system (CH3)3CBr + Cl3CBr

Autor
Del Barrio, M.; Tamarit, J. Ll.; Mondieig, D.; Negrier, P.
Tipus d'activitat
Article en revista
Revista
Journal of physical chemistry B
Data de publicació
2011-02-02
Volum
115
Número
7
Pàgina inicial
1679
Pàgina final
1688
DOI
https://doi.org/10.1021/jp109702t Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/11592 Obrir en finestra nova
Resum
The phase diagram of the two-component systems (CH(3))(3)CBr + Cl(3)CBr has been experimentally determined by means of differential scanning calorimetry and X-ray powder diffraction techniques from the low-temperature ordered phases to the liquid state. Before melting, both components have the same orientationally disordered (OD) face-centered cubic (FCC) and rhombohedral (R) phases, and the two-phase equilibria [FCC + L] and [R + FCC] are accounted for by means of the existence of an isomorphic...
Citació
Del Barrio, M. [et al.]. From figh-temperature orientationally disordered mixed crystals to low-temperature complex formation in the two-component system (CH3)3CBr + Cl3CBr. "Journal of physical chemistry B", 02 Febrer 2011, vol. 115, núm. 7, p. 1679-1688.
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
GCM - Grup de Caracterització de Materials

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