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An efficient and reusable catalyst based on Pd/CeO2 for the room temperature aerobic Suzuki–Miyaura reaction in water/ethanol

Autor
Amoroso, F.; Colussi, S.; Del Zotto, A.; Llorca, J.; Trovarelli, A.
Tipus d'activitat
Article en revista
Revista
Journal of molecular catalysis A. Chemical
Data de publicació
2010
Volum
315
Número
2
Pàgina inicial
197
Pàgina final
204
DOI
https://doi.org/10.1016/j.molcata.2009.09.012 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/11584 Obrir en finestra nova
Resum
The Pd/CeO2 system behaves as an efficient precatalyst for the Suzuki–Miyaura cross-coupling under mild conditions (298 K, in air) in ethanol/water. A broad range of aryl bromides, including those deactivated, and arylboronic acids underwent Suzuki–Miyaura coupling with quantitative GC yields of asymmetric biaryls. Isolated yields and purity of the coupling products were good to excellent. A careful investigation through a series of suitable tests unequivocally showed that the C–C cross-co...
Citació
Amoroso, F. [et al.]. An efficient and reusable catalyst based on Pd/CeO2 for the room temperature aerobic Suzuki–Miyaura reaction in water/ethanol. "Journal of molecular catalysis A. Chemical", 2010, vol. 315, núm. 2, p. 197-204.
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
NEMEN - Nanoenginyeria de materials aplicats a l'energia

Participants

  • Amoroso, Francesco  (autor)
  • Colussi, Sara  (autor)
  • del Zotto, Alessandro  (autor)
  • Llorca Pique, Jordi  (autor)
  • Trovarelli, Alessandro  (autor)