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PdO hydrate as an efficient and recyclable catalyst for the Suzuki-Miyaura reaction in water/ethanol at room temperature

Autor
Amoroso, F.; Colussi, S.; Del Zotto, A.; Llorca, J.; Trovarelli, A.
Tipus d'activitat
Article en revista
Revista
Catalysis communications
Data de publicació
2011-02-12
Volum
12
Número
6
Pàgina inicial
563
Pàgina final
567
DOI
https://doi.org/10.1016/j.catcom.2010.11.026 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/11795 Obrir en finestra nova
Resum
PdO·1.4H2O 1 prepared in our laboratories, as well as commercially available palladium oxides 2–4 have been found to act as efficient catalysts for the Suzuki–Miyaura reaction in ethanol/water mixture at room temperature in air. Thus, in the presence of 1 mol% catalyst, the reaction between different aryl bromides and arylboronic acids afforded a wide range of functionalized biphenyls in quantitative yield. Catalyst 1 has shown to be the most active for all couples of substrates, and it can...
Citació
Amoroso, F. [et al.]. PdO hydrate as an efficient and recyclable catalyst for the Suzuki-Miyaura reaction in water/ethanol at room temperature. "Catalysis communications", 12 Febrer 2011, vol. 12, núm. 6, p. 563-567.
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
NEMEN - Nanoenginyeria de materials aplicats a l'energia

Participants

  • Amoroso, Francesco  (autor)
  • Colussi, Sara  (autor)
  • del Zotto, Alessandro  (autor)
  • Llorca Pique, Jordi  (autor)
  • Trovarelli, Alessandro  (autor)