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Effect of the environment on the reactivity of 4´-substituted flavones and isoflavones

Autor
Armelin, E.; Donate, P.; Galembeck, S.
Tipus d'activitat
Article en revista
Revista
Tetrahedron
Data de publicació
2000-07
Volum
56
Número
29
Pàgina inicial
5105
Pàgina final
5111
DOI
https://doi.org/10.1016/S0040-4020(00)00437-3 Obrir en finestra nova
URL
http://www.sciencedirect.com/science/article/pii/S0040402000004373 Obrir en finestra nova
Resum
The reactivity of flavones and isoflavones, substituted at the 4' position by several types of electron-withdrawing or electron-donating groups, was studied by FMO theory in the gas-phase and in aqueous solution. The predictions of this theory were consistent with the experimental reactivity of analogue compounds, and also with the stability of the products of reaction of these compounds with different nucleophilic and electrophilic reagents. The preferences found in the gas-phase for the sites ...
Paraules clau
Linear Free Energy Relations, Substituent Effects, Solvents And Solvent Effects, Theoretical Studies
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
IMEM - Innovació, Modelització i Enginyeria en (BIO) Materials

Participants