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Dynamics of orientationally disordered mixed crystal sharing Cl-adamantane and CN-adamantane

Author
Martinez, J.; Capaccioli, S.; Berart, S.; Tamarit, J. Ll.; Del Barrio, M.; Veglio, N.; Pardo, L.
Type of activity
Journal article
Journal
Journal of non-crystalline solids
Date of publication
2010-01-27
Volume
11-17
Number
356
First page
621
Last page
624
DOI
10.1016/jnoncrysol.2009.04.075
Repository
http://hdl.handle.net/2117/7353 Open in new window
Abstract
Orientationally disordered (OD) mixed crystals formed between cyanoadamantane (CN-A) and chloroadamantane (Cl-A) have been thermodynamically characterized by means of thermal analysis and X-ray diffraction. The dynamics of these OD mixed crystals has been studied by means of broad band dielectric spectroscopy. Results evidence that dynamics of the α-relaxation process associated with the overall molecular tumbling slows down when molecules of CN-A are substituted by molecules of Cl-A.
Citation
Martinez, J. [et al.]. Dynamics of orientationally disordered mixed crystal sharing Cl-adamantane and CN-adamantane. "Journal of non-crystallne solids", 27 Gener 2010, vol. 11-17, núm. 356, p. 621-624.
Group of research
CRnE - Barcelona Research Center in Multiscale Science and Engineering
GCM - Group of Characterization of Materials
GRPFM - Research Group in Physical Properties of the Materials

Participants