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Graphene-supported palladium phosphide PdP2 nanocrystals for ethanol electrooxidation

Autor
Liu, J.; Luo, Z.; Junshan, L.; Yu, X.; Llorca, J.; Nasiou, D.; Arbiol , J.; Meyns, M.; Cabot, A.
Tipus d'activitat
Article en revista
Revista
Applied catalysis B. Environmental
Data de publicació
2019-03-01
Volum
242
Pàgina inicial
258
Pàgina final
266
DOI
https://doi.org/10.1016/j.apcatb.2018.09.105 Obrir en finestra nova
Repositori
http://hdl.handle.net/2117/124560 Obrir en finestra nova
URL
https://www.sciencedirect.com/science/article/pii/S0926337318309482 Obrir en finestra nova
Resum
We present a procedure to produce single-phase PdP2 nanocrystals (NCs). The approach involves the reaction of palladium(II) acetylacetonate and hexamethylphosphoroustriamide to nucleate defective Pd5P2 nanoparticles that subsequently, with further phosphorous incorporation, crystallize into PdP2. The synthesized PdP2 NCs were supported on reduced graphene oxide (rGO) and applied as electrocatalysts for ethanol oxidation. The activity of PdP2 toward the ethanol oxidation reaction (EOR) was over a...
Paraules clau
Colloidal synthesis, Electrocatalysis, Ethanol oxidation, Palladium diphosphide
Grup de recerca
CRnE - Centre de Recerca en Ciència i Enginyeria Multiescala de Barcelona
NEMEN - Nanoenginyeria de materials aplicats a l'energia

Participants

  • Liu, Junfeng  (autor)
  • Luo, Zhishan  (autor)
  • Junshan, Li  (autor)
  • Yu, Xiaoting  (autor)
  • Llorca Pique, Jordi  (autor)
  • Nasiou, Déspina  (autor)
  • Arbiol, Jordi  (autor)
  • Meyns, Michaela  (autor)
  • Cabot, Andreu  (autor)