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Graphene-supported palladium phosphide PdP2 nanocrystals for ethanol electrooxidation

Author
Liu, J.; Luo, Z.; Junshan, L.; Yu, X.; Llorca, J.; Nasiou, D.; Arbiol , J.; Meyns, M.; Cabot, A.
Type of activity
Journal article
Journal
Applied catalysis B. Environmental
Date of publication
2019-03-01
Volume
242
First page
258
Last page
266
DOI
https://doi.org/10.1016/j.apcatb.2018.09.105 Open in new window
Repository
http://hdl.handle.net/2117/124560 Open in new window
URL
https://www.sciencedirect.com/science/article/pii/S0926337318309482 Open in new window
Abstract
We present a procedure to produce single-phase PdP2 nanocrystals (NCs). The approach involves the reaction of palladium(II) acetylacetonate and hexamethylphosphoroustriamide to nucleate defective Pd5P2 nanoparticles that subsequently, with further phosphorous incorporation, crystallize into PdP2. The synthesized PdP2 NCs were supported on reduced graphene oxide (rGO) and applied as electrocatalysts for ethanol oxidation. The activity of PdP2 toward the ethanol oxidation reaction (EOR) was over a...
Citation
Liu, J., Luo, Z., Junshan, L., Yu, X., Llorca, J., Nasiou, D., Arbiol , J., Meyns, M., Cabot, A. Graphene-supported palladium phosphide PdP2 nanocrystals for ethanol electrooxidation. "Applied catalysis B. Environmental", 1 Març 2019, vol. 242, p. 258-266.
Keywords
Colloidal synthesis, Electrocatalysis, Ethanol oxidation, Palladium diphosphide
Group of research
CRnE - Barcelona Research Center in Multiscale Science and Engineering
NEMEN - Nanoengineering of Materials Applied to Energy

Participants

  • Liu, Junfeng  (author)
  • Luo, Zhishan  (author)
  • Junshan, Li  (author)
  • Yu, Xiaoting  (author)
  • Llorca Pique, Jordi  (author)
  • Nasiou, Déspina  (author)
  • Arbiol, Jordi  (author)
  • Meyns, Michaela  (author)
  • Cabot, Andreu  (author)